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(-C6H10O5-)n\(+nH_2O\overset{t^0}{\rightarrow}nC_6H_{12}O_6\)
C6H12O6\(\overset{t^0}{\rightarrow}2C_2H_5OH+2CO_2\)
\(\rightarrow\)(-C6H10O5-)n\(\overset{t^0}{\rightarrow}2nC_2H_5OH+2nCO_2\)
-Cứ 162n gam tinh bột tạo ra 92n gam rượu etylic
Vậy 106 gam tinh bột tạo ra x gam rượu etylic
x=\(\dfrac{10^6.92}{162}gam\)
Vì gạo có 80% tinh bột và hiệu suất quá trình là 60% nên:
\(V_{C_2H_5OH}=\dfrac{10^6\dfrac{92}{162}}{0,8}.\dfrac{80}{100}.\dfrac{60}{100}\approx0,34.10^6ml=0,34m^3\)
a, \(n_{C_2H_4}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\)
PT: \(C_2H_4+H_2O\underrightarrow{^{t^o,xt}}C_2H_5OH\)
Theo PT: \(n_{C_2H_5OH\left(LT\right)}=n_{C_2H_4}=0,7\left(mol\right)\)
Mà: H = 90%
\(\Rightarrow n_{C_2H_5OH\left(TT\right)}=0,7.90\%=0,63\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH\left(TT\right)}=0,63.46=28,98\left(g\right)\)
\(\Rightarrow V_{C_2H_5OH}=\dfrac{28,98}{0,8}=36,225\left(ml\right)\)
b, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
Theo PT: \(n_{CH_3COOH}=n_{C_2H_5OH}=0,63\left(mol\right)\)
\(\Rightarrow m_{CH_3COOH}=0,63.60=37,8\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{37,8}{5\%}=756\left(g\right)\)
a, \(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PT: \(C_2H_6O+3O_2\underrightarrow{t^o}2CO_2+3H_2O\)
Theo PT: \(n_{CO_2}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{15}\left(mol\right)\Rightarrow V_{CO_2}=\dfrac{2}{15}.22,4=\dfrac{224}{75}\left(l\right)\)
b, \(n_{C_2H_6O\left(LT\right)}=\dfrac{1}{3}n_{O_2}=\dfrac{1}{15}\left(mol\right)\)
Mà: H = 90%
\(\Rightarrow n_{C_2H_6O\left(TT\right)}=\dfrac{\dfrac{1}{15}}{90\%}=\dfrac{2}{27}\left(mol\right)\)
\(\Rightarrow m_{C_2H_6O}=\dfrac{2}{27}.46=\dfrac{92}{27}\left(g\right)\)
Ta có glucozo → 2C2H5OH + 2CO2
nrượu = 100 . 0,9 . 0,8 : 46 = 1,565 mol
=> mglucozo = 1,565 : 2 : 0,90 . 180 = 156,5 kg
\(V_{C_2H_5OH}=100.1000.90\%=9000\left(ml\right)\\ m_{C_2H_5OH}=9000.0,8=7200\left(g\right)\\ n_{C_2H_5OH}=\dfrac{7200}{46}=\dfrac{3600}{23}\left(mol\right)\)
PTHH: C6H12O6 -men rượu-> CO2 + C2H5OH
\(m_{C_6H_{12}O_6}=\dfrac{180.\dfrac{3600}{23}}{90\%}=\dfrac{720000}{23}\left(g\right)\)
a, \(C_2H_6O+3O_2\underrightarrow{t^o}2CO_2+3H_2O\)
b, \(n_{C_2H_6O}=\dfrac{23}{46}=0,5\left(mol\right)\)
Theo PT: \(n_{O_2}=3n_{C_2H_6O}=1,5\left(mol\right)\)
\(\Rightarrow V_{O_2}=1,5.22,4=33,6\left(l\right)\)
c, \(V_{C_2H_6O}=\dfrac{100.46}{100}=46\left(ml\right)\)
\(\Rightarrow m_{C_2H_6O}=46.0,8=36,8\left(g\right)\)
\(\Rightarrow n_{C_2H_6O}=\dfrac{36,8}{46}=0,8\left(mol\right)\)
PT: \(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\)
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{C_2H_5ONa}=0,4\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,4.22,4=8,96\left(l\right)\)
Đổi 10kg = 10000g
Ta có: \(n_{CH_3COOH\left(LT\right)}=\dfrac{10000.5\%}{92\%}=\dfrac{12500}{23}\left(mol\right)\)
PTHH:
\(C_2H_5OH+O_2\xrightarrow[]{\text{men giấm}}CH_3COOH+H_2O\)
\(\dfrac{12500}{23}\)<---------------------\(\dfrac{12500}{23}\)
\(\Rightarrow m_{C_2H_5OH}=\dfrac{12500}{23}.46=25000\left(g\right)=25\left(kg\right)\)
Ta có:
\(V_{C2H5OH}=0,2.96\%=0,192\left(l\right)=192\)
\(\Rightarrow m_{C2H5OH}=192.0,8=153,6\left(g\right)\)
\(\Rightarrow n_{C2H5OH}=\frac{153,6}{46}=3,339\left(mol\right)\)
\(n_{C2H5OH\left(lt\right)}=\frac{3,339}{90\%}=3,71\left(mol\right)=V_{C2H4}=3,21.22,4=83,104\left(l\right)\)