a, \(Fe+H_2SO_{4\text{loãng}}\rightarrow FeSO_4+H_2\)

\(n_{Fe}=n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

\(Fe+H_2SO_{4\text{đặc}}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+H_2O\)

\(Cu+H_2SO_{4\text{đặc}}\rightarrow CuSO_4+SO_2+H_2O\)

Bảo toàn e:

\(2n_{Cu}+3n_{Fe}=2n_{SO_2}\)

\(\Leftrightarrow n_{Cu}=\dfrac{2n_{SO_2}-3n_{Fe}}{2}=0,25\left(mol\right)\)

\(\Rightarrow x=m_{Cu}+m_{Fe}=0,25.64+0,5.56=44\left(g\right)\)

a) Đặt \(\left\{{}\begin{matrix}n_{Cu}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)

Ta có: \(\left\{{}\begin{matrix}n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)=b=n_{Fe}\\n_{SO_2}=\dfrac{22,4}{22,4}=1\left(mol\right)\end{matrix}\right.\)

Bảo toàn electron: \(2a+3b=2\) \(\Rightarrow2a+3\cdot0,5=2\) \(\Rightarrow a=n_{Cu}=0,25\left(mol\right)\)

\(\Rightarrow x=m_{Cu}+m_{Fe}=0,25\cdot64+0,5\cdot56=44\left(g\right)\)

b) Ta có: \(n_{H_2SO_4\left(p/ư\right)}=\dfrac{1}{2}n_{e\left(traođổi\right)}+n_{SO_2}=\dfrac{1}{2}\cdot2+1=2\left(mol\right)\)

\(\Rightarrow\Sigma n_{H_2SO_4\left(đặc\right)}=2\cdot110\%=2,2\left(mol\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{2,2\cdot98}{98\%}=220\left(g\right)\) \(\Rightarrow V_{H_2SO_4}=\dfrac{220}{1,84}\approx119,57\left(ml\right)\)

c) Ta có: \(\left\{{}\begin{matrix}n_{SO_2}=1\left(mol\right)\\n_{Ba\left(OH\right)_2}=0,4\cdot1,5=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo 2 muối

PTHH: \(2SO_2+Ba\left(OH\right)_2\rightarrow Ba\left(HSO_3\right)_2\)

              2x                 x                    x          (mol)

            \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3\downarrow+H_2O\)

              y             y                                      (mol)

Ta lập được hệ phương trình: \(\left\{{}\begin{matrix}x+y=0,6\\2x+y=1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=n_{Ba\left(HSO_3\right)_2}=0,4\left(mol\right)\\y=0,2\end{matrix}\right.\)

\(\Rightarrow C_{M_{Ba\left(HSO_3\right)_2}}=\dfrac{0,4}{0,4}=1\left(M\right)\)

\(H_2S + CuSO_4 \to CuS + H_2SO_4\)

\(n_{H_2S} = n_{CuSO_4} = \dfrac{800.1,2.10\%}{160} = 0,6(mol)\\\)

Gọi : \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\)⇒ 56x + 65b = 37,2(1)

\(Fe +S \xrightarrow{t^o}FeS\\ Zn + S\xrightarrow{t^o}ZnS\\ FeS + 2HCl \to FeCl_2 + H_2S\\ ZnS + 2HCl \to ZnCl_2 + H_2S\\\)

Theo PTHH : 

\(n_{H_2S} = a + b = 0,6(2)\)

Từ (1)(2) suy ra a = 0,2; b = 0,4

Vậy :

\(m_{Fe} = 0,2.56 = 11,2(gam)\\ m_{Zn} = 0,4.65 = 26(gam)\)

\(n_{Fe}=a\left(mol\right),n_{FeO}=b\left(mol\right)\)

\(m_X=56a+72b=12.8\left(g\right)\)

\(n_{H_2}=n_{Fe}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)

\(\Rightarrow a=0.1\)

\(b=\dfrac{12.8-56\cdot0.1}{72}=0.1\left(mol\right)\)

\(BTe:\)

\(3n_{Fe}+n_{FeO}=2n_{SO_2}\)

\(\Rightarrow n_{SO_2}=\dfrac{3\cdot0.1+0.1}{2}=0.2\left(mol\right)\)

\(V_{SO_2}=0.2\cdot22.4=4.48\left(l\right)\)

\(\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)

\(n_{H_2}=n_{Fe}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

=> \(n_{FeO}=\dfrac{12,8-56.0,1}{72}=0,1\left(mol\right)\)

12,8 g hh X ------> 0,1 mol Fe và 0,1 mol FeO

=> 6,4g hh X ------> 0,05 mol Fe và 0,05 mol FeO

2Fe + 6H2SO4 → Fe2(SO4)3 + 3SO2 + 6H2O

2FeO + 4H2SO4 → 4H2O + Fe2(SO4)3 + SO2

=> \(n_{SO_2}=\dfrac{3}{2}n_{Fe}+\dfrac{1}{2}n_{FeO}=0,1\left(mol\right)\)

SO2 + Ca(OH)2→ CaSO3 + H2O

Vì kết tủa nên khối lượng dung dịch giảm : \(m_{thêm}-m_{mất}=0,1.64+0,1.74-0,1.120=1,8\left(g\right)\)

Fe+ H2SO4 -> FeSO4 + H2

0,1___0,1______0,1__0,1(mol)

FeO+ H2SO4-> FeSO4 + H2O

=>mFe= 0,1.56=5,6(g)

=>%mFe=(5,6/12.8).100=43.75%

=>%mFeO=56,25%

6,4gam hh X => Số mol giảm đi 1/2

nFe=0,05(mol)=nCu

PTHH: 2 Fe + 6 H2SO4(đ)-to-> Fe2(SO4)3 + 3 SO2 + 6 H2O

0,05_______0,15__________0,025________0,075(mol)

Cu+ 2 H2SO4(đ) -to-> CuSO4 + SO2 + H2O

0,05___0,1_________0,05____0,05(mol)

=> nSO2=0,125(mol)

PTHH: SO2 + Ca(OH)2 -> CaSO3 + H2O

0,125_______0,125_____0,125(mol)

=> KL dung dịch giảm.

KL giảm:

0,125.64 + 0,125.74 - 0,125.120=2,25(g)

Chúc em học tốt!