Bài 1 :

Ta có : \(\left\{{}\begin{matrix}m_{H2SO4}=39,2\\m_{HNO3}=12,6\end{matrix}\right.\) \(\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{H2SO4}=\dfrac{m}{M}=0,4\\n_{HNO3}=\dfrac{m}{M}=0,2\end{matrix}\right.\) \(\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\left\{{}\begin{matrix}n_H=2.0,4=0,8\\n_S=0,4.1=0,4\\n_O=4.0,4=1,6\end{matrix}\right.\\\left\{{}\begin{matrix}n_H=0,2.1=0,2\\n_N=0,2.1=0,2\\n_O=0,2.3=0,6\end{matrix}\right.\end{matrix}\right.\) ( mol )

\(\Rightarrow\left\{{}\begin{matrix}n_O=1,6+0,6=2,2\\n_N=0,2\\n_S=0,4\end{matrix}\right.\) ( mol )

Vậy ....

Bài 2 :

\(CH_4+2O_2\rightarrow CO_2+2H_2O\)

\(C_2H_6+\dfrac{7}{2}O_2\rightarrow2CO_2+3H_2O\)

\(TheoPTHH:n_{O2}=2n_{CH4}+\dfrac{7}{2}n_{C2H6}=1,25\left(mol\right)\)

\(\Rightarrow V=n.22,4=28\left(l\right)\)

\(n_{hh}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)

\(n_{CH_4}=a\left(mol\right),n_{H_2}=b\left(mol\right)\)

\(\Rightarrow a+b=0.5\left(1\right)\)

\(n_{H_2O}=2a+b=\dfrac{12.6}{18}=0.7\left(mol\right)\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.2,b=0.3\)

\(n_{CO_2}=n_{CH_4}=0.2\left(mol\right)\)

\(V=0.2\cdot22.4=4.48\left(l\right)\)

Đáp án: B

Sau khi đốt cháy hoàn toàn, hỗn hợp A gồm $CO_2$ và $O_2$ dư.

Ta có:

$M_A=1,25\cdot M_{O_2}=1,25\cdot32=40g/mol$

Gọi $x$ là % thể tích $CO_2$.

$40=44x+32(1-x)$

$40=44x+32-32x$

$8=12x$

$x=\dfrac{2}{3}$

$%V_{CO_2}=\dfrac{2}{3}\cdot100=66,67%$

$%V_{O_2}=100-66,67=33,33%$

Khi cho A vào $Ca(OH)_2$ dư:

$CO_2+Ca(OH)_2\rightarrow CaCO_3+H_2O$

$n_{CaCO_3}=\dfrac{6}{100}=0,06mol$

$n_{CO_2}=0,06mol$

Vì $CO_2$ chiếm $66,67%$:

$n_A=\dfrac{0,06}{2/3}=0,09mol$

$n_{O_2\ dư}=0,09-0,06=0,03mol$

Theo:

$C+O_2\rightarrow CO_2$

$n_C=n_{CO_2}=0,06mol$

$m_C=0,06\cdot12=0,72g$

Số mol $O_2$ ban đầu:

$n_{O_2}=n_{O_2\ phản\ ứng}+n_{O_2\ dư}$

$n_{O_2}=0,06+0,03=0,09mol$

$V_{O_2}=0,09\cdot22,4=2,016L$

Hỗn hợp A:

$M_A=19,2\cdot2=38g/mol$

Với $M_{O_2}=32,\ M_{O_3}=48$.

Gọi $x$ là phần mol $O_3$:

$38=32(1-x)+48x$

$38=32+16x$

$x=0,375$

$%V_{O_3}=37,5%$

$%V_{O_2}=62,5%$

Hỗn hợp B:

$M_B=3,6\cdot2=7,2g/mol$

Với $M_{H_2}=2,\ M_{CO}=28$.

Gọi $x$ là phần mol $CO$:

$7,2=2(1-x)+28x$

$7,2=2+26x$

$x=0,2$

$%V_{CO}=20%$

$%V_{H_2}=80%$

Trong $1mol$ B:

$n_{H_2}=0,8mol$

$n_{CO}=0,2mol$

Phản ứng:

$2H_2+O_2\rightarrow2H_2O$

$2CO+O_2\rightarrow2CO_2$

Lượng $O_2$ cần:

$n_{O_2}=0,8\cdot\dfrac12+0,2\cdot\dfrac12$

$n_{O_2}=0,5mol$

Trong $1mol$ A có:

$n_{O_2}=0,625mol$

$n_{O_3}=0,375mol$

Mỗi $1mol\ O_3$ cung cấp lượng oxi tương đương:

$O_3\rightarrow\dfrac32O_2$

Lượng $O_2$ tương đương trong $1mol$ A:

$n_{O_2,tđ}=0,625+0,375\cdot\dfrac32$

$n_{O_2,tđ}=1,1875mol$

Gọi số mol A cần dùng là $n$:

$1,1875n=0,5$

$n=\dfrac{0,5}{1,1875}\approx0,421mol$

\(n_{CaCO_3}=\dfrac{25}{100}=0.25\left(mol\right)\)

\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)

\(0.25...........0.25...........0.25\)

\(C_{M_{Ca\left(OH\right)_2}}=\dfrac{0.25}{0.1}=2.5\left(M\right)\)

\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)

\(0.25..............0.25\)

\(V_{CH_4}=0.25\cdot22.4=5.6\left(l\right)\)

a) nCaCO3=0,25(mol)

CH4 + 2 O2 -to-> CO2 + 2 H2O

0,25<------------------0,25(mol)

CO2 + Ca(OH)2 -> CaCO3 + H2O

0,25<------0,25-----------0,25(mol)

b) CMddCa(OH)2= 0,25/0,1= 2,5(M)

b) V(CH4,đktc)=0,25.22,4=5,6(l)

a) \(n_{Na}=\dfrac{2,3}{23}=0,1\left(mol\right)\)

PTHH: 4Na + O₂ --t^o--> 2Na₂O

______0,1->0,025----->0,05

=> V_O2 = 0,025.22,4 = 0,56(l)

b) 

PTHH: Na₂O + H₂O --> 2NaOH

______0,05----------->0,1

=> \(C_{M\left(NaOH\right)}=\dfrac{0,1}{0,2}=0,5M\)

Có: \(\dfrac{M_A}{M_{O_2}}=\dfrac{\dfrac{m_A}{n_A}}{\dfrac{m_{O_2}}{n_{O_2}}}=\dfrac{m_A}{m_{O_2}}.\dfrac{n_{O_2}}{n_A}=1.\dfrac{V_{O_2}}{V_A}=\dfrac{1}{2}\)

=> \(M_A=\dfrac{1}{2}.M_{O_2}=16\left(g/mol\right)\)

=> A là CH₄

PTHH: CH₄ + 2O₂ --t^o--> CO₂ + 2H₂O

              1---->2

=> V_O2 = 2.22,4 = 44,8 (l)