nAl= 1,08 : 27=0,04(mol) 
pthh : 2Al +6HCl -t--> 2AlCl3  +3H2 
          0,04--------------->0,04----->0,06 (mol)
=> VH2 (đktc)= 0,06.22,4 = 1,344 (l) 
 

nAl= 1,08 : 27=0,04(mol) 
pthh : 2Al +6HCl -t--> 2AlCl3  +3H2 
          0,04----->0,04---->0,06 (mol)
=> VH2 (đktc)= 0,06.22,4 = 1,344 (l) 

a) \(PT:CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)

\(HCl+NaOH\rightarrow NaOH+H_2O\)

b) \(m_{HCl}=\frac{200.10,95\%}{100\%}=21,9\left(g\right)\)

\(n_{HCl}=\frac{21,9}{36,5}=0,6\left(mol\right)\)

c) \(n_{NaOH}=2.0,05=0,1\left(mol\right)\Rightarrow n_{HCl\left(pưNaOH\right)}=0,1\left(mol\right)\)

\(\Rightarrow n_{HCl\left(pưCaCO_3\right)}=0,6-0,1=0,5\left(mol\right)\)

d) \(n_{CaCO_3}=\frac{1}{2}n_{HCl\left(pưCaCO_3\right)}=0,5.\frac{1}{2}=0,25\left(mol\right)\)

\(m_{CaCO_3}=0,25.100=25\left(g\right)\)

e) \(n_{CO_2}=n_{CaCO_3}=0,25\left(mol\right)\)

\(V_{CO_2}=0,25.22,4=5,6\left(l\right)\)

f) \(n_{CaCl_2}=n_{CaCO_3}=0,25\left(mol\right)\)

\(m_{ddA}=25+200-0,25.44=214\left(g\right)\)

\(C\%_{ddCaCl_2}=\frac{0,25.111}{214}.100\%=12,97\%\)

\(C\%_{ddHCldư}=\frac{0,1.36,5}{214}.100\%=1,71\%\)

\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)

PTHH:

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

0,2                      0,2          0,3 

\(V_{H_2}=n.22,4=6,72\left(l\right)\)

\(m_{AlCl_3}=n.M=0,2.133,5=26,7\left(g\right)\)

a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

b) \(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\) ;    \(n_{HCl}=\dfrac{m}{M}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

 \(2Al\)    \(+\)   \(6HCl\)    →    \(2AlCl_3\)  \(+\)  \(3H_2\)

Tỉ lệ:   \(\dfrac{0,2}{2}>\dfrac{0,5}{6}\)                                          ⇒  Al dư, tính theo HCl

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

           \(0,5\)    →   \(\dfrac{1}{6}\)    →   \(0,25\)       ( mol )

\(V_{H_2}=n.22,4=0,25.22,4=5,6\left(l\right)\)

c) \(m_{AlCl_3}=n.M=\dfrac{1}{6}.\left(27+35,5.3\right)=22,25\left(g\right)\)

\(n_{Al}=\frac{10,8}{27}=0,4\left(mol\right)\) 

\(2Al+6HCl->2AlCl_3+3H_2\) (1)

theo (1) \(n_{H_2}=\frac{3}{2}n_{Al}=0,6\left(mol\right)\) 

=> \(V_{H_2}=0,6.22,4=13,44\left(l\right)\)

a.

\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

0,2                                               0,3    ( mol )

\(V_{H_2}=0,3.22,4=6,72l\)

\(n_{Fe_3O_4}=\dfrac{46,4}{232}=0,2mol\)

\(Fe_3O_4+4H_2\rightarrow\left(t^o\right)3Fe+4H_2O\)

\(\dfrac{0,2}{1}\) >  \(\dfrac{0,3}{4}\)                                     ( mol )

0,2                                0,6                ( mol )

a là Sắt ( Fe )

\(m_{Fe}=0,6.56=33,6g\)

\(1.a.2Al+6HCl\rightarrow2AlCl_3+3H_2\\ b.n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ TheoPT:n_{AlCl_3}=n_{Al}=0,4\left(mol\right)\\ \Rightarrow m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\\ c.TheoPT:n_{H_2}=\dfrac{3}{2}n_{Al}=0,6\left(mol\right)\\ \Rightarrow V_{H_2}=0,6.22,4=13,44\left(l\right)\)

\(2.a.Mg+2HCl\rightarrow MgCl_2+H_2\\ b.n_{HCl}=\dfrac{25,55}{36,5}=0,7\left(mol\right)\\ TheoPT:n_{Mg}=\dfrac{1}{2}n_{HCl}=0,35\left(mol\right)\\ \Rightarrow m_{Mg}=0,35.24=8,4\left(g\right)\\ c.TheoPT:n_{H_2}=\dfrac{1}{2}n_{HCl}=0,35\left(mol\right)\\ \Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)

n hh khí = 0.5 mol 
nCO: x mol 
nCO2: y mol 
=> x + y = 0.5 
28x + 44y = 17.2 g 
=> x = 0.3 mol 
y = 0.2 mol 
Khối lượng oxi tham gia pứ oxh khử oxit KL: 0.2 * 16 = 3.2g => m KL = 11.6 - 3.2 = 8.4g 
TH: KL hóa trị I => nKL = 2*nH2 = 0.3 mol => KL: 28!! 
KL hóa trị III => nKL = 2/3 *nH2 = 0.1 mol => KL: 84!! 
KL hóa trị II => nKL = nH2 = 0.15 mol => KL: 56 => Fe. 
nFe / Oxit = 0.15 mol 
nO/Oxit = 0.2 mol 
=> nFe/nO = 3/4 => Fe3O4 
Fe3O4 + 4CO = 3Fe + 4CO2 
Fe + H2SO4 = FeSO4 + H2 
0.15.....0.15.......0.15.....0.15 
=> mH2SO4 pứ = 14.7 g => mdd = 147 g 
m dd sau khi cho KL vào = m KL + m dd - mH2 thoát ra = 0.15 * 56 + 147 - 0.15*2 = 155.1g 
=> C% FeSO4 = 14.7% 

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