\(n_{BaCl_2}=0.2\cdot0.5=0.1\left(mol\right)\)

\(BaCl_2+K_2SO_4\rightarrow BaSO_4+2KCl\)

\(0.1.............0.1.........................0.2\)

\(V_{dd_{K_2SO_4}}=\dfrac{0.1}{1}=0.1\left(l\right)\)

\(V_{dd}=0.2+0.1=0.3\left(l\right)\)

\(C_{M_{KCl}}=\dfrac{0.2}{0.3}=0.67\left(M\right)\)

Đổi 200ml = 0,2 lít

Ta có: \(n_{BaCl_2}=0,5.0,2=0,1\left(mol\right)\)

a. PTHH: \(BaCl_2+K_2SO_4--->BaSO_4\downarrow+2KCl\)

Theo PT: \(n_{K_2SO_4}=n_{BaCl_2}=0,1\left(mol\right)\)

\(\Rightarrow V_{dd_{K_2SO_4}}=\dfrac{0,1}{1}=0,1\left(lít\right)\)

b. Theo PT: \(n_{KCl}=2.n_{BaCl_2}=2.0,1=0,2\left(mol\right)\)

Ta có: \(V_{dd_{KCl}}=V_{dd_{BaCl_2}}=0,1\left(lít\right)\)

\(\Rightarrow C_{M_{KCl}}=\dfrac{0,2}{0,1}=2M\)

500ml=0.5l

nBaOH2 =0.5 x1=0.5 mol

MH2SO4=500.15%=75g

nH2SO4= xấp xỉ 0.8mol

H2SO4 dư tính theo BaOH2

pthh: Ba(OH)2 + H2SO4 => BaSO4+H2O

Theo pthh nBaSO4= nBa(OH)2=0.5mol

=>m kết tủa= 0.5x233=116.5g

theo pthh nH2SO4 phản ứng=nBaOH2= 0.5 mol

=> nH2SO4 Dư=0.8-0.5=0.3 mol

=>

m dư=0.3x98=29.4g

mH2SO4 đã dùng là m phản ứng? nếu thế thì m đã dung là 75-29.4=45.6

còn nếu m đã dùng là m chất tan thi là 75g như trên =))

làm tắt v:

\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)

Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)

Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)

\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)

a, Có: \(n_{NaOH}=0,4.1=0,4\left(mol\right)\)

\(n_{HCl}=0,2.1,5=0,3\left(mol\right)\)

PT: \(NaOH+HCl\rightarrow NaCl+H_2O\)

Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,3}{1}\), ta được NaOH dư.

Theo PT: \(n_{NaOH\left(pư\right)}=n_{HCl}=0,3\left(mol\right)\)

\(\Rightarrow n_{NaOh\left(dư\right)}=0,1\left(mol\right)\Rightarrow m_{NaOH\left(dư\right)}=0,1.40=4\left(g\right)\)

b, Khi cho quỳ tím vào dd A thì quỳ tím chuyển xanh do trong A còn dd NaOH dư.

c, Theo PT: \(n_{NaCl}=n_{HCl}=0,3\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{NaCl}}=\dfrac{0,3}{0,4+0,2}=0,5M\\C_{M_{NaOH\left(dư\right)}}=\dfrac{0,1}{0,4+0,2}=\dfrac{1}{6}M\end{matrix}\right.\)

Bạn tham khảo nhé!

\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)

\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)

\(a)n_{NaOH}=0,5.0,2=0,1mol\\ n_{H_2SO_4}=0,3.1=0,3mol\\2 NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ \Rightarrow\dfrac{0,1}{2}< \dfrac{0,3}{1}\Rightarrow H_2SO_4.dư\\ 2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

0,1                  0,05             0,05            0,1

\(C_M\) \(_{Na_2SO_4}=\dfrac{0,05}{0,2+0,3}=0,1M\)

\(C_M\) \(_{H_2SO_4}=\dfrac{0,3-0,05}{0,2+0,3}=0,5M\)

b) Vì H₂SO₄ dư nên quỳ tím hoá đỏ.

\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+H_2O\)

\(a\) \(2a\)

\(H_2SO_4+2KOH\rightarrow K_2SO_4+H_2O\)

\(b\) \(2b\)

Sau pư (1) đổi màu quỳ tìm \(\Rightarrow H_2SO_4\) dư \(n_{KON}=0,02.0,5=0,01\left(mol\right)\)

\(\rightarrow n_{H_2SO_4dư}=\frac{1}{2}n_{KOU}=5.10^{-3}\left(MOL\right)\)

\(\rightarrow n_{H_2O_4\text{ban đầu }}=0,05.1=0,05\left(mol\right)\)

\(\rightarrow n_{H_2SO_4\left(\text{pư 1 }\right)}=0,05-5.10^{-3}=0,045\left(mol\right)\)

\(\rightarrow n_{NaOH}=0,045.2=0,09\left(mol\right)\)

\(\rightarrow CM_{NaOH}=\frac{0,09}{0,05}=1,8\left(M\right)\)

phần đầu của phần b nên có câu lí luận thì sẽ chặt chẽ hơn:

Bài 8: Bạn bổ sung thêm đề phần này nhé.

Bài 9: Bài này giống bài 2 bên dưới nhé.

Bài 10: 

\(n_{Fe\left(NO_3\right)_3}=0,3.1=0,3\left(mol\right)\)

PT: \(Fe\left(NO_3\right)_3+3NaOH\rightarrow3NaNO_3+Fe\left(OH\right)_3\)

a, \(n_{NaOH}=3n_{Fe\left(NO_3\right)_3}=0,9\left(mol\right)\Rightarrow V_{NaOH}=\dfrac{0,9}{2}=0,45\left(l\right)\)

b, \(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)

Theo PT: \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_2}=\dfrac{1}{2}n_{Fe\left(NO_3\right)_3}=0,15\left(mol\right)\)

\(\Rightarrow m_{Fe_2O_3}=0,15.160=24\left(g\right)\)

Bài 11:

Ta có: \(n_{NaOH}=\dfrac{200.12\%}{40}=0,6\left(mol\right)\)

PT: \(2NaOH+FeCl_2\rightarrow2NaCl+Fe\left(OH\right)_2\)

a, \(n_{FeCl_2}=n_{Fe\left(OH\right)_2}=\dfrac{1}{2}n_{NaOH}=0,3\left(mol\right)\Rightarrow C\%_{FeCl_2}=\dfrac{0,3.127}{100}.100\%=38,1\%\)

b, \(n_{NaCl}=n_{NaOH}=0,6\left(mol\right)\)

Ta có: m _{dd sau pư} = 200 + 100 - 0,3.90 = 273 (g)

\(\Rightarrow C\%_{NaCl}=\dfrac{0,6.58,5}{273}.100\%\approx12,86\%\)

\(n_{NaOH}=\dfrac{50\cdot20\%}{40}=0.25\left(mol\right)\)

\(n_{HNO_3}=\dfrac{84\cdot15\%}{63}=0.2\left(mol\right)\)

\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)

Lập tỉ lệ : 

\(\dfrac{0.25}{1}>\dfrac{0.2}{1}\Rightarrow NaOHdư\)

Vì : NaOH dư nên quỳ tím sẽ hóa xanh.

\(m_{dd}=50+84=134\left(g\right)\)

\(n_{NaNO_3}=0.2\left(mol\right)\)

\(n_{NaOH\left(dư\right)}=0.25-0.2=0.05\left(mol\right)\)

\(C\%_{NaNO_3}=\dfrac{0.2\cdot85}{134}\cdot100\%=12.68\%\)

\(C\%_{NaOH\left(dư\right)}=\dfrac{0.05\cdot40}{134}\cdot100\%=1.49\%\)