a) \(Zn+2HCl->ZnCl_2+H_2\)

        x..........2x.........................x................x

\(2Al+6HCl->2AlCl_3+3H_2\)

    y.............3y................................y..............1,5y

b) Gọi số mol của Zn và Al lần lượt là x và y 

n H2 = 7,616:22,4=0,34 mol =>  x+1,5y= 0,34 mol

Ta có m muối = 136x+1335y=34,96 g

=> x=0,1 mol , y=0,16 mol

=> a = 65.0,1+27.0,16=10,82 g

V HCl = \(\frac{2.0,1+3.0,16}{1}=0,68lit\)

\(n_{HCl}=0,8.0,5=0,4\left(mol\right);n_{H_2SO_4}=0,8.0,75=0,6\left(mol\right)\)

=> \(n_{Cl^-}=0,4\left(mol\right);n_{SO_4^{2-}}=0,6\left(mol\right)\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Bảo toàn nguyên tố H:

\(n_{HCl}.1+n_{H_2SO_4}.2=n_{H_2}.2+n_{H_2O}.2\)

\(\Leftrightarrow0,4.1+0,6.2=0,2.2+n_{H_2O}.2\)

=>\(n_{H_2O}=0,6\left(mol\right)\)

=> \(n_O=0,6\left(mol\right)\)

\(m_{muối}=m_{kimloai}+m_{Cl^-}+m_{SO_4^{2-}}\)

=>\(m_{kimloai}=88,7-35,5.0,4-0,6.96=16,9\left(g\right)\)

=> \(m=m_{kimloai}+m_O=16,9+0,6.16=26,5\left(g\right)\)

Phản ứng xảy ra:

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Có:

\(m_{\text{muối}}=m_{kl}+m_{Cl}\rightarrow32,65=14,9+m_{Cl}\)

\(\rightarrow m_{Cl}=17,75g\rightarrow n_{Cl}=0,5mol=n_{HCl}\)

\(\rightarrow m_{HCL}=0,5.36,5=18,25g\)

\(\rightarrow m=m_{ddHCl}=\frac{18,25}{10\%}=182,5g\)

Mg+2HCl->MgCl2+H2

x---------2x

Fe+2HCl->MgCl2+H2

y------2y

Ta có :\(\left\{{}\begin{matrix}24x+56y=6\\2x+2y=0,2\end{matrix}\right.\)

=>số âm kiểm tra lại đề

2A+2aHCl->2ACla+aH2

2B+2bHCl->2BClb+aH2

nH2=0.3(mol)

->nHCl=0.3*2=0.6(mol)

->nCl/HCl=0.6(mol)

m muối khan=m kim loại+mCl/HCl=8+0.6*35.5=29.3(g)