a) $n_{O_2} = 0,15(mol)$

\(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)

0,3                         0,15           0,15       0,15                    (mol)

$H = \dfrac{0,15.158}{63,2}.100\% = 37,5\%$

b)

$m_B = 63,2 - 0,15.32 = 58,4(gam)$
$\%m_{K_2MnO_4} = \dfrac{0,15.197}{58,4}.100\% = 50,59\%$

$\%m_{MnO_2} = \dfrac{0,15.87}{58,4}.100\% = 22,35\%$
$\%m_{KMnO_4\ dư} = 100\% -50,59\% -22,35\% = 27,06\%$

1) \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

m_A = m_KMnO4(bđ) - m_O2 = 79 - 0,15.32 = 74,2 (g)

PTHH: 2KMnO₄ --t^o--> K₂MnO₄ + MnO₂ + O₂

               0,3<-----------0,15<----0,15<---0,15

=> \(H=\dfrac{0,3.158}{79}.100\%=60\%\)

2) 

\(\left\{{}\begin{matrix}\%m_{K_2MnO_4}=\dfrac{0,15.197}{74,2}.100\%=39,825\%\\\%m_{MnO_2}=\dfrac{0,15.87}{74,2}.100\%=17,588\%\\\%m_{KMnO_4\left(không.pư\right)}=\dfrac{79-0,3.158}{74,2}.100\%=42,587\%\end{matrix}\right.\)

3) \(n_{KMnO_4\left(không.pư\right)}=\dfrac{79}{158}-0,3=0,2\left(mol\right)\)

PTHH: 2KMnO₄ + 16HCl --> 2KCl + 2MnCl₂ + 5Cl₂ + 8H₂O

                 0,2----------------------------------->0,5

             K₂MnO₄ + 8HCl --> 2KCl + MnCl₂ + 2Cl₂ + 4H₂O

                 0,15-------------------------------->0,3

              MnO₂ + 4Hcl --> MnCl₂ + Cl₂ + 2H₂O

                0,15------------------->0,15

=> \(V_{Cl_2}=22,4\left(0,5+0,3+0,15\right)=21,28\left(l\right)\)

\(n_{KMnO_4}=\dfrac{79}{158}=0,5mol\)

\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)

\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)

0,5                                                  0,15

a)\(m_{KMnO_4}=0,15\cdot197=29,55g\)

\(m_{MnO_2}=0,15\cdot87=13,05g\)

\(m_{CRắn}=m_{KMnO_4}+m_{MnO_2}=29,55+13,05=42,6g\)

\(n_{KMnO_4pư}=0,15\cdot2=0,3mol\)

\(H=\dfrac{0,3}{0,5}\cdot100\%=60\%\)

b)\(m_{O_2}=0,15\cdot32=4,8g\)

\(\%m_{K_2MnO_4}=\dfrac{29,55}{42,6}\cdot100\%=69,37\%\)

\(\%m_{MnO_2}=100\%-69,37\%=30,63\%\)

\(n_{KMnO_4}=\dfrac{79}{158}=0,5mol\)

\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)

0,5                                                 0,25

\(H=80\%\Rightarrow n_{O_2}=0,25\cdot80\%=0,2mol\)

\(\Rightarrow V=0,2\cdot22,4=4,48l\)

\(a)n_{KMnO_4} = a; n_{KClO_3} = b\Rightarrow 158a + 122,5b = 99,95(1)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ 2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\\ n_{O_2} = 0,5a +1,5b = \dfrac{14,56}{22,4}=0,65(2)\\ (1)(2)\Rightarrow a = 0,4 ; b = 0,3\\ \%m_{KMnO_4} = \dfrac{0,4.158}{99,95}.100\% = 63,23\%\\ \%m_{KClO_3} = 100\%-63,23\% = 36,77\%\)

\(n_{K_2MnO_4} = n_{MnO_2} = 0,5a = 0,2(mol)\\ n_{KClO_3} = b = 0,3(mol)\\ m_{hh\ sau\ pư} = 99,95 - 0,65.32 = 79,15(gam)\\ \%m_{K_2MnO_4} = \dfrac{0,2.197}{79,15}.100\% = 49,78\%\\ \%m_{MnO_2} = \dfrac{0,2.87}{79,15},100\% = 21,98\%\\ \%m_{KCl} = 28,24\%\)

ko khó lém bn ơi có câu nèo easy hơm ko

\(2KClO_3\xrightarrow[]{t^0}2KCl+3O_2\)

1mol                1mol          1,5mol

0,2mol                                0,3mol

⇒Khi nhiệt phân 1 mol KClO₃ thì thu được số mol O₂ bằng 1,5 mol. Để thu được 0,3 mol O₂ thì cần số mol KClO₃ bằng 0,2 mol.

Bảo toàn khối lượng : 

$m_{CO_2} = 12 - 7,6 = 4,4(gam)$
$n_{CaO} = n_{CaCO_3\ pư} = n_{CO_2} = \dfrac{4,4}{44} = 0,1(mol)$

$H = \dfrac{0,1.100}{12}.100\% = 83,33\%$

$\%m_{CaO} = \dfrac{0,1.56}{7,6}.100\% = 73,68\%$
$\%m_{CaCO_3} = 100\% -73,68\% = 26,32\%$

\(n_{CaCO_3}=\dfrac{12}{100}=0,12\left(mol\right)\\ PTHH:CaCO_3\underrightarrow{to}CaO+CO_2\\ x.........x........x\left(mol\right)\\ m_{rắn}=m_{CaCO_3\left(còn\right)}+m_{CaO}=\left(12-100x+56x\right)=7,6\\ \Leftrightarrow x=0,1\left(mol\right)\\ H=\dfrac{0,1}{0,12}.100\approx83,333\%\)