Bài 14 : 

Vì metan không tác dụng với Brom nên : 

\(n_{C2H4Br2}=\dfrac{4,7}{188}=0,025\left(mol\right)\)

a) Pt : \(C_2H_4+Br_2\rightarrow C_2H_4Br_{2|}\)

              1          1                1

            0,025                    0,025

b) \(n_{C2H4}=\dfrac{0,025.1}{1}=0,025\left(mol\right)\)

\(V_{C2H4\left(dktc\right)}=0,025.22,4=0,56\left(l\right)\)

\(V_{CH4\left(dktc\right)}=1,4-0,56=0,84\left(l\right)\)

⁰/₀V_CH4 = \(\dfrac{0,84.100}{1,4}=60\)⁰/₀

⁰/₀V_C2H4 = \(\dfrac{0,56.100}{1,4}=40\)⁰/₀

 Chúc bạn học tốt

\(n_{hh}=\dfrac{6,72}{22,4}=0,3mol\)

\(n_{C_2H_4Br_2}=\dfrac{16}{188}=\dfrac{4}{47}mol\)

\(\Rightarrow n_{etilen}=\dfrac{4}{47}mol\)

\(\Rightarrow n_{metan}=0,3-\dfrac{4}{47}=\dfrac{101}{470}mol\)

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(\%V_{etilen}=\dfrac{\dfrac{4}{47}}{0,3}\cdot100\%=28,37\%\)

\(\%V_{metan}=100\%-28,37\%=71,63\%\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

\(CH_3COOH+Na\rightarrow CH_3COONa+\dfrac{1}{2}H_2\)

 0,1                                0,1

\(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\)

0,1                           0,1

Theo pthh có: \(n_A=2nH_2=2.0,1=0,2\left(mol\right)\)

Gọi x, y là số mol của rượu và axit có trong hh A.

có hệ: \(\left\{{}\begin{matrix}x+y=0,2\\60x+46y=10,6\end{matrix}\right.\)

=> x = y = 0,1

=> \(\left\{{}\begin{matrix}\%_{m_{CH_3COOH}}=\dfrac{60.0,1.100}{10,6}=56,6\%\\\%_{m_{C_2H_5OH}}=100-56,6=43,4\%\end{matrix}\right.\)

\(m_{muối}=m_{CH_3COONa}+m_{C_2H_5ONa}=82.0,1+68.0,1=15\left(g\right)\)

1. \(n_{Br_2}=0,4.0,5=0,2\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,2\left(mol\right)\Rightarrow V_{C_2H_4}=0,2.22,4=4,48\left(l\right)\)

2. \(n_{C_2H_4Br_2}=\dfrac{9,4}{188}=0,05\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,05\left(mol\right)\)

\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,05.22,4}{1,4}.100\%=80\%\)

\(\Rightarrow\%V_{CH_4}=100-80=20\%\)

Cho hỗn hợp qua dung dịch brom dư

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Khí thoát ra là \(CH_4\)

\(CH_4+2O_2\rightarrow^{t^o}CO_2+2H_2O\)

\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)

Ta có:

\(n_{CaCO_3}=\frac{40}{100}=0,4mol=n_{CO_2}=n_{CH_4}\)

\(\rightarrow V_{CH_4}=0,4.22,4=8,96l\)

\(\rightarrow\%V_{CH_4}=\frac{8,96}{13,56}=66\%\rightarrow\%V_{C_2H_4}=34\%\)

\(C_2H_5OH+K_2CO_3\rightarrow\left(kopứ\right)\)

\(2CH_3COOH+K_2CO_3\rightarrow2CH_3COOK+CO_2+H_2O\)

    2                      1                  2                    1           1       (mol)

  0,4                     0,2              0,4                0,2         0,2 (mol)

\(nCO_2=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

\(mCH_3COOH=0,4.60=24\left(g\right)\)

\(mK_2CO_3=0,2.138=27,6\left(g\right)\)

\(mCH_3COOK=0,4.98=39,2\left(g\right)\)

\(mCO_2=0,2.44=8,8\left(g\right)\)

\(mdd=mCH_3COOH+mK_2CO_3+mCH_3COOK-mCO_2\)

\(=24+27,6+39,2-8,8=82\left(g\right)\)

\(C\%m_{CH_3COOH}=\dfrac{24.100}{82}=29,27\%\)

\(C\%m_{K_2CO_3}=\dfrac{27,6.100}{82}=33,66\%\)

câu thứ 2 bn tự lm cho bt:>

a) PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

b) Ta có: \(n_{Br_2}=\dfrac{11,2}{160}=0,07\left(mol\right)=n_{C_2H_4}\)

\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,07\cdot22,4}{1,72}\cdot100\%\approx91,16\%\) 

\(\Rightarrow\%V_{CH_4}=8,84\%\)

a) \(C_2H_4 + Br_2 \to C_2H_4Br_2\)

b)

\(n_{C_2H_4} = n_{Br_2} = \dfrac{5,6}{160} = 0,035(mol)\\ \%V_{C_2H_4} = \dfrac{0,035.22,4}{0,86}.100\% = 91,16\%\\ \%V_{CH_4} = 100\% - 91,16\% = 8,84\%\)

a, PT: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

b, \(n_{Br_2}=\dfrac{5,6}{160}=0,035\left(mol\right)\)

Theo PT: \(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,0175\left(mol\right)\)

\(\Rightarrow\%V_{C_2H_2}=\dfrac{0,0175.22,4}{0,86}.100\%\approx45,58\%\)

\(\Rightarrow\%V_{CH_4}\approx54,42\%\)