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a,VddC2H5OH=23+27=50(ml)
Đr=\(\dfrac{23}{50}\).100=46o
b,mC2H5OH=23.0,8=18,4(g)
nC2H5OH=\(\dfrac{18,4}{46}\)=0,4(mol)
PTHH: 2C2H5OH + 2K ---> 2C2H5OK + H2
0,4-------------------------------------->0,2
=> VH2 = 0,2.24 = 4,8 (l
a,VddC2H5OH=23+27=50(ml)
Đr=2350.100=46ob, mC2H5OH=23.0,8=18,4(g)
nC2H5OH=18,446=0,4(mol)a,
VddC2H5OH=23+27=50(ml)Đr=2350.100=46ob,
mC2H5OH=23.0,8=18,4(g)
nC2H5OH=18,446=0,4(mol)
PTHH: 2C2H5OH + 2K ---> 2C2H5OK + H2
0,4-------------->0,2
=> VH2 = 0,2.24 = 4,8 (l)
\(a,V_{ddC_2H_5OH}=23+27=50\left(ml\right)\\ Đ_r=\dfrac{23}{50}.100=46^o\\ b,m_{C_2H_5OH}=23.0,8=18,4\left(g\right)\\ n_{C_2H_5OH}=\dfrac{18,4}{46}=0,4\left(mol\right)\)
PTHH: 2C2H5OH + 2K ---> 2C2H5OK + H2
0,4-------------------------------------->0,2
=> VH2 = 0,2.24 = 4,8 (l)
\(a,V_{C_2H_5OH}=\dfrac{96.30}{100}=28,8\left(ml\right)\\ \rightarrow m_{C_2H_5OH}=28,8.0,8=23,04\left(ml\right)\\ \rightarrow n_{C_2H_5OH}=\dfrac{23,04}{46}=0,5\left(mol\right)\)
PTHH: 2C2H5OH + 2Na ---> 2C2H5ONa + H2
0,5----------------------------------->0,25
\(\rightarrow V_{H_2}=0,25.22,4=5,6\left(l\right)\)
b, \(n_{CH_3COOH}=\dfrac{36}{60}=0,6\left(mol\right)\)
PTHH: \(C_2H_5OH+CH_3COOH\xrightarrow[t^o]{H_2SO_{4\left(đ\right)}}CH_3COOC_2H_5+H_2O\)
LTL: 0,5 < 0,6 => CH3COOH dư
Theo pthh: nCH3COOH = nC2H5OH = 0,5 (mol)
=> meste = 0,5.88.70% = 30,8 (g)
a. Ta có: \(V_{rượu}=\dfrac{96.100}{100}=96\left(ml\right)\)
\(\Rightarrow m_{rượu}=0,8.96=76,8\left(g\right)\)
b. Ta có: \(n_{rượu}=\dfrac{76,8}{46}=\dfrac{192}{115}\left(mol\right)\)
\(2C_2H_5OH+2Na->2C_2H_5ONa+H_2\)
\(\dfrac{192}{115}\left(mol\right)\) \(\dfrac{96}{115}\left(mol\right)\)
\(\Rightarrow V_{H_2}=\dfrac{96}{115}.22,4\approx18,7\left(l\right)\)
100 ml dd rượi etylic 96 độ có 96 ml rượi etylic và 4 ml nước
ta có mC2H5OH=0,8*96=76,8 G suy ra nC2H5OH=192/115 mol
pt 2C2H5OH+2NA------->2C2H5ONA+H2 1
THEO PT 1 n H2=1/2nC2H5OH=96/115 mol
pt H2O+NA------->NAOH+1/2H2
ta có vH2O=4 ml ==>mH2O=4 mol=>nH2O=2/9 mol
vậy tổng nH2=1094/1035 mol =>vh2=23,7 l
Đặt:
nC2H5OH= x mol
nCH3COOH= y mol
mhh= 46x + 60y= 7.6g (1)
nH2= 1.68/22.4=0.075 mol
C2H5OH + Na --> C2H5ONa + 1/2H2
x___________________________0.5x
CH3COOH + Na --> CH3COONa + 1/2H2
y______________________________0.5y
nH2= 0.5x + 0.5y= 0.075 mol (2)
Giải (1) và (2):
x= 0.1
y= 0.05
mC2H5OH= 4.6g
mCH3COOH= 3g
2/ VC2H5OH= 10*96/100=9.6ml
VH2O= Vhh- Vr= 10-9.6=0.4 g
mH2O= 0.4g
nH2O= 1/45 mol
mC2H5OH= 9.6*0.8=7.68g
nC2H5OH= 0.16 mol
C2H5OH + Na --> C2H5ONa + 1/2H2
0.167_________________________0.0835
Na + H2O --> NaOH + 1/2H2
______1/45___________1/90
nH2= 0.0835+1/90=0.095 mol
VH2= 22.128l
\(a,V_{C_2H_5OH}=\dfrac{10.96}{100}=9,6\left(ml\right)\\ m_{C_2H_5OH}=9,6.0,8=7,68\left(g\right)\\ n_{C_2H_5OH}=\dfrac{7,68}{46}=\dfrac{96}{575}\left(mol\right)\)
PTHH: 2C2H5OH + 2Na ---> 2C2H5ONa + H2
\(\dfrac{96}{575}\)------------------------------------->\(\dfrac{48}{575}\)
\(V_{H_2}=\dfrac{48}{575}.22,4=1,87\left(l\right)\)
\(b,V_{dd}=12+10,6=20,6\left(ml\right)\\ Đ_r=\dfrac{9,6}{20,6}.100=46,6^o\)